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Nickel(II) removal by mixtures of Acorga M5640 and DP8R in pseudo-emulsion based hollow fiber with strip dispersion technology

机译:采用带分散技术的伪乳液基中空纤维中Acorga M5640和DP8R的混合物去除镍(II)

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摘要

This work presents the investigation of Ni(II) extraction from aqueous solution through pseudo-emulsion\udbased hollow fiber strip dispersion (PSEHFSD) containing the mixture 2-hydroxy-5-nonylbenzaldehyde\udoxime + di(2-ethylhexyl) phosphoric acid/Exxsol D100 as extractant in the form of a pseudo-emulsion\udwith H2SO4. The organic and aqueous strip phases are separated when the stirring device is stopped.\udThe permeation of Ni(II) is investigated as a function of various experimental variables: hydrodynamic\udconditions, feed pH, extractants mixture concentration in the pseudo-emulsion, initial Ni(II) concentration\udin feed phase, H2SO4 concentration in the pseudo-emulsion as strippant. In PEHFSD, pseudo-emulsion\udis an emulsion that is formed temporarily between organic and stripping solutions. In this\udinvestigation, feed was circulated through the lumen side in counter-current mode. The selectivity of\ud2-hydroxy-5-nonylbenzaldehyde oxime + di(2-ethylhexyl) phosphoric acid/Exxsol D100 based PEHFSD\udtoward different metals was also examined.
机译:这项工作提出了通过含有2-羟基-5-壬基苯甲醛\肟和二(2-乙基己基)磷酸/ Exxsol混合物的假乳液\ udbased中空纤维条分散液(PSEHFSD)从水溶液中提取Ni(II)的研究。 D100作为萃取剂,为假乳液/ H2SO4形式。停止搅拌设备时,有机相和水相汽提相分离。\ ud根据各种实验变量对Ni(II)的渗透进行了研究:流体动力学\条件,进料pH值,假乳液中萃取剂混合物的浓度,初始Ni(II)浓度\ udin进料阶段,假乳液中的H2SO4浓度作为汽提剂。在PEHFSD中,假乳液会乳化在有机溶液和汽提溶液之间临时形成的乳液。在该研究中,饲料以逆流模式在管腔侧循环。还研究了\ ud2-羟基-5-壬基苯甲醛肟+二(2-乙基己基)磷酸/ Exxsol D100的PEHFSD的选择性\对其他金属的选择性。

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